Three-Way Chemoselectivity Switching through Coupled Equilibria.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c02003
Abstract: Controlling the chemoselectivity of reactions operating on complex mixtures, including those found in biological and petrochemical feedstocks or in the primordial soup from which life emerged, is generally challenging. The selectivity of imine oxidation can… read more here.
Keywords: three way; chemoselectivity; coupled equilibria; chemoselectivity switching ... See more keywords
Controlling the length of porphyrin supramolecular polymers via coupled equilibria and dilution-induced supramolecular polymerization
Sign Up to like & getrecommendations! Published in 2022 at "Nature Communications"
DOI: 10.1038/s41467-021-27831-2
Abstract: Multi-component systems often display convoluted behavior, pathway complexity and coupled equilibria. In recent years, several ways to control complex systems by manipulating the subtle balances of interaction energies between the individual components have been explored… read more here.
Keywords: porphyrin; length; supramolecular polymers; coupled equilibria ... See more keywords