Tuning the Thermochemistry and Reactivity of a Series of Cu-Based 4H+/4e– Electron-Coupled-Proton Buffers
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DOI: 10.1021/acs.inorgchem.4c00835
Abstract: Electron-coupled-proton buffers (ECPBs) store and deliver protons and electrons in a reversible fashion. We have recently reported an ECPB based on Cu and a redox-active ligand that promoted 4H+/4e– reversible transformations (J. Am. Chem. Soc.2022,… read more here.
Keywords: series based; electron coupled; proton; coupled proton ... See more keywords
A 4H+/4e- Electron-Coupled-Proton Buffer Based on a Mononuclear Cu Complex.
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DOI: 10.1021/jacs.2c05454
Abstract: In this research article, we describe a 4H+/4e- electron-coupled-proton buffer (ECPB) based on Cu and a redox-active ligand. The protonated/reduced ECPB (complex 1: [Cu(8H+/14e-)]1+), consisting of CuI with 2 equiv of the ligand (catLH4: 1,1'-(4,5-dimethoxy-1,2-phenylene)bis(3-(tert-butyl)urea)),… read more here.
Keywords: coupled proton; electron coupled; proton buffer;
Using earth abundant materials for the catalytic evolution of hydrogen from electron-coupled proton buffers
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DOI: 10.1039/c7se00334j
Abstract: Hydrogen has a large array of uses throughout the chemical and energy industries, yet is largely produced through the reformation of fossil fuels. Renewable production of hydrogen, via electrolytic water splitting, could be key to… read more here.
Keywords: coupled proton; hydrogen; electron coupled; abundant materials ... See more keywords