Hydrogen Atom Transfer (HAT)-Triggered Iron-Catalyzed Intra- and Intermolecular Coupling of Alkenes with Hydrazones: Access to Complex Amines
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b03794
Abstract: A methodology for the coupling of alkenes with aldehyde- or ketone-derived Cbz-hydrazones to form a new C–C bond through a radical process is described. The sequence comprises an initial in situ generation of a putative… read more here.
Keywords: coupling alkenes; iron; hydrogen atom; atom transfer ... See more keywords
NiH-catalyzed C(sp3)-Si coupling of alkenes with vinyl chlorosilanes.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04232k
Abstract: A novel NiH-catalyzed highly regioselective coupling of alkenes with vinyl chlorosilanes, constructing C-Si bonds, is developed. Under mild reaction conditions, a series of benzyl organosilanes with various functional groups could be accessed. Further synthetic studies… read more here.
Keywords: alkenes vinyl; sp3 coupling; vinyl chlorosilanes; nih catalyzed ... See more keywords