Electrocatalytic N—N cross-coupling of N-alkyl-3-aminopyrazoles at a nickel anode
Sign Up to like & getrecommendations! Published in 2020 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-020-2995-0
Abstract: Azo(het)arenes are widely demanded compounds, among which are dyes,1 pharmacologically active substances,2 and energetic compounds.3 Previously, we developed effi cient and environmentally benign syntheses of azo(het)arenes by anodic N—N coupling of aminopyrazoles,4 aminofurazans,5 and aminofuroxans6.… read more here.
Keywords: het arenes; alkyl aminopyrazoles; coupling alkyl; cross ... See more keywords
Metal-free oxidative coupling of alkyl chlorides with thiols: An efficient access to sulfoxides
Sign Up to like & getrecommendations! Published in 2020 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2019.151492
Abstract: Abstract An efficient and step-economical access to sulfoxides from thiols and alkyl halides in the presence of I2O5 and DBU via direct oxidative couplings is described here. It is the first case that combined Williamson… read more here.
Keywords: free oxidative; access sulfoxides; coupling alkyl; oxidative coupling ... See more keywords
Nickel-Catalyzed C-S Reductive Cross-Coupling of Alkyl Halides with Arylthiosilanes toward Alkyl Aryl Thioethers.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01954
Abstract: A nickel-catalyzed C-S reductive cross-coupling of alkyl halides with arylthiosilanes for producing alkyl aryl thioethers is developed. This reaction is initiated by umpolung transformations of arylthiosilanes followed by C-S reductive cross-coupling with alkyl halides to… read more here.
Keywords: coupling alkyl; reductive cross; cross coupling; nickel catalyzed ... See more keywords
Copper-Catalyzed Cross-Coupling of Alkyl and Phosphorus Radicals for C(sp3)-P Bond Formation.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c02454
Abstract: A CuI-catalyzed cross-coupling of alkyl- and phosphorus-centered radicals for C(sp3)-P bond formation is introduced. Diacyl peroxides, generated in situ from aliphatic acids and H2O2, serve as a source for alkyl radicals and also an initiator… read more here.
Keywords: coupling alkyl; alkyl phosphorus; cross coupling; phosphorus ... See more keywords
Nickel/Photoredox Dual Catalytic Cross-Coupling of Alkyl and Amidyl Radicals to Construct C(sp3)–N Bonds
Sign Up to like & getrecommendations! Published in 2021 at "ACS Catalysis"
DOI: 10.1021/acscatal.1c00731
Abstract: The construction of C(sp3)–N bonds via direct radical–radical cross-coupling under benign conditions is a desirable but challenging approach. Herein, the cross-coupling of alkyl and amidyl radicals... read more here.
Keywords: cross coupling; alkyl amidyl; coupling alkyl; sp3 bonds ... See more keywords
Palladium Catalyzed Carbonylative Coupling of Alkyl Boron Reagents with Bromodifluoroacetamides
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b00420
Abstract: A catalytic protocol for the preparation of α,α-difluoro-β-alkyl-β-ketoamides is developed employing a Pd-mediated carbonylative Suzuki coupling between alkylboron reagents and bromodifluoroacetamides with COgen as the CO source. The reaction reveals good functional group tolerance providing… read more here.
Keywords: alkyl; carbonylative coupling; coupling alkyl; palladium catalyzed ... See more keywords
Asymmetric cross-coupling of alkyl, alkenyl and (hetero)aryl nucleophiles with racemic allyl halides.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc07151e
Abstract: Single enantiomer molecules are important for the pharmaceutical and agrochemical industries and increasingly so in materials science. Most strategies to obtain enantiomerically enriched molecules rely on either generating new stereogenic centres from prochiral substrates or… read more here.
Keywords: asymmetric cross; coupling alkyl; alkyl alkenyl; cross ... See more keywords
Suzuki-type cross-coupling of alkyl trifluoroborates with acid fluoride enabled by NHC/photoredox dual catalysis
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d1sc06102j
Abstract: The Suzuki–Miyaura cross-coupling of C(sp3)-hybridised boronic compounds still remains a challenging task, thereby hindering the broad application of alkyl boron substrates in carbon–carbon bond-forming reactions. Herein, we developed an NHC/photoredox dual catalytic cross-coupling of alkyl… read more here.
Keywords: coupling alkyl; cross coupling; suzuki; nhc photoredox ... See more keywords
Cu(II) Porphyrin-catalyzed Coupling of Alkyl Tosylates and Grignard Reagents
Sign Up to like & getrecommendations! Published in 2020 at "Chemistry Letters"
DOI: 10.1246/cl.200064
Abstract: Copper(II) porphyrin-catalyzed coupling of alkyl tosylates and alkyl Grignard reagents afforded substituted alkanes. The role of the copper(II) porphyrin complex was examined using EPR and in-situ ... read more here.
Keywords: grignard reagents; alkyl tosylates; porphyrin catalyzed; coupling alkyl ... See more keywords