Ligands and Bases Mediate Switching between Aminocarbonylations and Alkoxycarbonylations in Coupling of Aminophenols with Iodoarenes.
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DOI: 10.1021/acs.inorgchem.9b01392
Abstract: The mechanisms of aminocarbonylations and alkoxycarbonylations in coupling of aminophenols with iodoarenes catalyzed by the bidentate phosphorus ligand Pd complexes were explored with theoretical calculations. The origins of chemoselective carbonylation mediated by ligands and bases… read more here.
Keywords: coupling aminophenols; alkoxycarbonylations coupling; aminocarbonylations alkoxycarbonylations; ligands bases ... See more keywords