Ni/Photoredox-Catalyzed C(sp3)-C(sp3) Coupling between Aziridines and Acetals as Alcohol-Derived Alkyl Radical Precursors.
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DOI: 10.1021/jacs.2c09294
Abstract: Aziridines are readily available C(sp3) precursors that afford valuable β-functionalized amines upon ring opening. In this article, we report a Ni/photoredox methodology for C(sp3)-C(sp3) cross-coupling between aziridines and methyl/1°/2° aliphatic alcohols activated as benzaldehyde dialkyl… read more here.
Keywords: cross coupling; sp3; coupling aziridines; sp3 sp3 ... See more keywords
Solvent-controlled C2/C3-regioselective ring-opening/coupling of aziridines with amines and CS2: synthesis of 2-aminoethyl dithiocarbamates
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DOI: 10.1039/d4qo02148g
Abstract: This study presents a solvent-controlled C2/C3-regioselective ring-opening/coupling of aziridines with amines and CS2, yielding two distinct types of 2-aminoethyl dithiocarbamates without the need for additives or non-green activation strategy. Featuring... read more here.
Keywords: opening coupling; controlled regioselective; regioselective ring; ring opening ... See more keywords