Photocatalytic Oxidative Coupling of Benzyl Alcohol and Benzylamine for Imine Synthesis Using Immobilized Cs3Bi2Br9 Perovskite.
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DOI: 10.1002/smll.202409037
Abstract: The oxidative cross-coupling of benzyl alcohol (BA) and benzylamine (BZA) is employed for the production of the corresponding imine, N-benzylidenebenzylamine (BZI), under visible light irradiation (light-emitting diodes (LE with λmax = 417 nm) and mild reaction conditions.… read more here.
Keywords: benzyl alcohol; using immobilized; coupling benzyl; alcohol benzylamine ... See more keywords
Ligand-Controlled Chemoselectivity in Manganese-Catalyzed Coupling of Benzyl Alcohol with Phosphorus Ylide: A Theoretical Study.
Sign Up to like & getrecommendations! Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.5c04327
Abstract: The selective formation of C-C and C═C bonds is fundamentally important in pharmaceutical synthesis and materials science. Herein, the ligand-controlled chemoselectivity of the Mn-catalyzed coupling of benzyl alcohol (BnOH) with a phosphorus ylide for the… read more here.
Keywords: coupling benzyl; ligand controlled; controlled chemoselectivity; ligand ... See more keywords
Phosphine-Catalyzed Cross-Coupling of Benzyl Halides and Fumarates.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c01214
Abstract: A phosphine-catalyzed olefinic cross-coupling between benzyl halides and fumarates is described, which affords trisubstituted alkenes in good yields and excellent E-selectivity under metal-free conditions. Mechanistic studies suggest a catalytic cycle involving phosphorus ylide formation, Michael… read more here.
Keywords: phosphine catalyzed; coupling benzyl; halides fumarates; cross coupling ... See more keywords
Nickel-Catalyzed Decyanative Reductive Coupling of Benzyl Nitriles with Aryl Chlorides toward the Synthesis of Diarylmethanes.
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DOI: 10.1021/acs.orglett.5c04713
Abstract: Herein, nickel-catalyzed decyanative reductive cross-coupling of benzyl nitriles with aryl chlorides has been developed. The current protocol features a wide scope, good functional group compatibility, and excellent chemoselectivity, thus providing a powerful alternative to the… read more here.
Keywords: nitriles aryl; decyanative reductive; coupling benzyl; benzyl nitriles ... See more keywords
TBAI-Catalyzed Oxidative Coupling of Benzyl Ketones to Synthesize 2,3-Diaryl-1,4-Diketones in Water
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DOI: 10.1021/acsomega.1c06216.s001
Abstract: An efficient and green route of C–C bond formation was disclosed to construct 2,3-diaryl-1,4-diketones from α-methylene ketones by the catalysis of tetrabutylammonium iodide (TBAI) with tert-butyl hydroperoxide (TBHP) as an oxidant in water. This reaction… read more here.
Keywords: catalyzed oxidative; diaryl diketones; water; coupling benzyl ... See more keywords
Design of Hemilabile N,N,N-Ligands in Copper-Catalyzed Enantioconvergent Radical Cross-Coupling of Benzyl/Propargyl Halides with Alkenylboronate Esters.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c00957
Abstract: The enantioconvergent radical C(sp3)-C(sp2) cross-coupling of alkyl halides with alkenylboronate esters is an appealing tool in the assembly of synthetically valuable enantioenriched alkenes owing to the ready availability, low toxicity, and air/moisture stability of alkenylboronate… read more here.
Keywords: enantioconvergent radical; coupling benzyl; cross coupling; halides alkenylboronate ... See more keywords