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Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c04358
Abstract: The first enantioselective decarboxylative Negishi-type alkylations of α-oxy carboxylic acids are reported via the intermediacy of redox-active esters (RAEs). This transformation enables a radical-based retrosynthesis of seemingly trivial enantiopure dialkyl carbinols. This article includes a…
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Keywords:
dialkyl;
synthesis;
coupling development;
enantioselective dialkyl ... See more keywords