Oxidative Coupling of [Ge9(Si(SiMe3)3)2]2- with f Elements.
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DOI: 10.1021/acs.inorgchem.2c03971
Abstract: We report the reactions of K2[Ge9(Hyp)2] (Hyp = Si(SiMe3)3) with (thf)3YbI3, ThI4, and UCl4, leading to the oxidative coupling of the metalloid germanium cluster to form the dimeric dianion [Ge18(Hyp)4]2-. The novel dimerized Ge18-cluster was… read more here.
Keywords: sime3 elements; coupling ge9; ge18 hyp; ge9 sime3 ... See more keywords