Cobalt-Catalyzed Regio-, Diastereo-, and Enantioselective Reductive Coupling of Internal Alkynes with Cyclobutenes.
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DOI: 10.1021/acs.orglett.5c01695
Abstract: Herein, we report the cobalt-catalyzed asymmetric ene-yne reductive coupling of internal alkynes and unactivated cyclobutenes. The reaction produced densely functionalized chiral vinyl cyclobutanes in up to 92% yields with excellent absolute and relative stereocontrol (>99%… read more here.
Keywords: catalyzed regio; coupling internal; reductive coupling; cobalt catalyzed ... See more keywords
Capturing the Complex Relationship Between Internal and External Training Load: A Data-Driven Approach.
Sign Up to like & getrecommendations! Published in 2023 at "International journal of sports physiology and performance"
DOI: 10.1123/ijspp.2022-0493
Abstract: BACKGROUND Training load is typically described in terms of internal and external load. Investigating the coupling of internal and external training load is relevant to many sports. Here, continuous kernel-density estimation (KDE) may be a… read more here.
Keywords: training load; training; external training; coupling internal ... See more keywords
Hydrogenative Cross-coupling of Internal Alkynes and Aryl Iodides by Palladium/Copper Cooperative Catalysis
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DOI: 10.1246/cl.170961
Abstract: The hydrogenative cross-coupling of internal alkynes and aryl iodides by palladium/copper cooperative catalysis furnished a range of triarylethenes in moderate to good yield and stereoselectivity. Under the applied catalytic conditions, various functional groups, including silylether,… read more here.
Keywords: hydrogenative cross; internal alkynes; aryl iodides; alkynes aryl ... See more keywords