Reductive Coupling of Ketones: Contrasting the Reactivity of an Aluminyl and a Gallyl Anion.
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DOI: 10.1021/acs.inorgchem.4c05519
Abstract: The synthesis of a new potassium gallyl system, K[Ga(NON)] ([NON]2- = [O(SiMe2NDipp)2]2-, Dipp = 2,6-iPr2C6H3), has been reported, and its reactivity toward a variety of ketones has been studied. The potassium gallyl is initially isolated… read more here.
Keywords: aluminyl; coupling ketones; reductive coupling; ketones contrasting ... See more keywords
Studies Toward Improved Enantiocontrol in the Asymmetric Cu-Catalyzed Reductive Coupling of Ketones and Allenamides: 1,2-Aminoalcohol Synthesis.
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DOI: 10.1021/acs.orglett.3c00157
Abstract: Herein, we report the development of an improved system for the Cu-catalyzed enantioselective reductive coupling of ketones and allenamides through the optimization of the allenamide to avoid an on-cycle rearrangement. High enantioselectivities could be obtained… read more here.
Keywords: ketones allenamides; reductive coupling; studies toward; coupling ketones ... See more keywords