Enantioselective C(sp3)–C(sp3) cross-coupling of non-activated alkyl electrophiles via nickel hydride catalysis
Sign Up to like & getrecommendations! Published in 2020 at "Nature chemistry"
DOI: 10.1038/s41557-020-00576-z
Abstract: Cross-coupling of two alkyl fragments is an efficient method to produce organic molecules rich in sp3-hybridized carbon centres, which are attractive candidate compounds in drug discovery. Enantioselective C(sp3)–C(sp3) coupling is challenging, especially of alkyl electrophiles… read more here.
Keywords: sp3; nickel hydride; coupling non; non activated ... See more keywords
Capturing the interplay between spin–orbit coupling and non-Condon effects on the photoabsorption spectra of Ru and Os dyes
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Chemistry C"
DOI: 10.1039/c8tc06403b
Abstract: A theoretical protocol developed to study the low-energy tail of the absorption spectrum of homoleptic biscyclometalated ruthenium and osmium complexes. read more here.
Keywords: interplay spin; capturing interplay; orbit coupling; coupling non ... See more keywords