Catalytic Oxidative Coupling of Phenols and Related Compounds.
Sign Up to like & getrecommendations! Published in 2022 at "ACS catalysis"
DOI: 10.1021/acscatal.2c00318
Abstract: Phenols and their derivatives are the elementary building blocks for several classes of complex molecules that play essential roles in biological systems. Nature has devised methods to selectively couple phenolic compounds, and many efforts have… read more here.
Keywords: catalytic oxidative; coupling; related compounds; oxidative coupling ... See more keywords
Cu4Ti4-oxo clusters functionalized by in situ - generated 2,2'-biphenolate ligands from the oxidative coupling of phenols.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt03756d
Abstract: Herein, we report a twisted cubic Cu(I)4Ti(IV)4-oxo cluster stabilized by in situ - formed 2,2'-biphenolate ligands from the oxidative coupling of phenols. The 2,2'-biphenolate-functionalized Cu(I)4Ti(IV)4O4 cluster shows short Cu⋯C contacts and exhibits smaller HOMO-LUMO gaps… read more here.
Keywords: oxidative coupling; coupling phenols; ligands oxidative; biphenolate ligands ... See more keywords
Nickel-Catalyzed Suzuki Coupling of Phenols Enabled by SuFEx of Tosyl Fluoride
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28020636
Abstract: A practical and efficient Suzuki coupling of phenols has been developed by using trans-NiCl(o-Tol)(PCy3)2/2PCy3 as a catalyst in the presence of tosyl fluoride as an activator. The key for the direct use of phenols lies… read more here.
Keywords: coupling phenols; tosyl fluoride; suzuki coupling; one pot ... See more keywords