Control of Interchain Antiferromagnetic Coupling in Porous Co(II)-Based Metal-Organic Frameworks by Tuning the Aromatic Linker Length: How Far Does Magnetic Interaction Propagate?
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DOI: 10.1021/acs.inorgchem.7b00899
Abstract: Three MOF-74-type Co(II) frameworks with one-dimensional hexagonal channels have been prepared. Co(II) spins in a chain are ferromagnetically coupled through carboxylate and phenoxide bridges. Interchain antiferromagnetic couplings via aromatic ring pathways operate over a Co-Co… read more here.
Keywords: length; coupling porous; antiferromagnetic coupling; control interchain ... See more keywords