Insights Into the Magnesium‐Catalyzed Catalyzed C‐C Coupling of Terminal Alkynes with Carbodiimides.
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DOI: 10.1002/ejoc.202400702
Abstract: The bis‐guanidinate anion stabilized amido magnesium (II) compound [LMgN(SiMe3)2; L = {(ArHN)(ArN)‐C=N−C=(NAr)(NHAr); Ar = 2,6‐Et2‐C6H3}] (Mg‐1) has been synthesized and characterized. It has been successfully employed as a pre‐catalyst for the catalytic C‐C coupling of… read more here.
Keywords: magnesium; terminal alkynes; coupling terminal; insights magnesium ... See more keywords