Covalency Competition in the Quadruple Perovskite CdCu3Fe4O12.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b01405
Abstract: Cadmium ions (Cd2+) are similar to calcium ions (Ca2+) in size, whereas the Cd2+ ions tend to form covalent bonds with the neighboring anions because of the high electronegativity. The covalent Cd-O bonds affect other… read more here.
Keywords: perovskite cdcu3fe4o12; quadruple perovskite; covalency; covalency competition ... See more keywords
Covalency competition dominates the water oxidation structure–activity relationship on spinel oxides
Sign Up to like & getrecommendations! Published in 2020 at "Nature Catalysis"
DOI: 10.1038/s41929-020-0465-6
Abstract: Spinel oxides have attracted growing interest over the years for catalysing the oxygen evolution reaction (OER) due to their efficiency and cost-effectiveness, but fundamental understanding of their structure–property relationships remains elusive. Here we demonstrate that… read more here.
Keywords: spinel; covalency competition; spinel oxides; activity ... See more keywords