Articles with "covalent" as a keyword



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Covalent Adaptable Networks with Dual Dynamic Covalent Bonds for Self‐Repairing Infrared Transmitting Materials

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Published in 2024 at "Advanced Functional Materials"

DOI: 10.1002/adfm.202315469

Abstract: Infrared transmitting materials (IRTMs) are prone to mechanical and corrosion damage during long‐time exposure to harsh outside environments. However, conventional IRTMs frequently lack self‐repairability that limit their lifespan. To address the limitation, thioctic acid‐based epoxy… read more here.

Keywords: dual dynamic; covalent; self repairing; infrared transmitting ... See more keywords

Pure Zwitterionic Hydrogel with Mechanical Robustness and Dynamic Tunability Enabled by Synergistic Non‐Covalent Interactions

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Published in 2024 at "Advanced Functional Materials"

DOI: 10.1002/adfm.202409594

Abstract: Zwitterionic hydrogels with exceptional antifouling properties and biocompatibility have gained widespread attention in biomedical applications. However, achieving robust mechanical performance while maintaining high water content within a single‐network zwitterionic hydrogel remains challenging. Traditional covalent crosslinking… read more here.

Keywords: zwitterionic hydrogel; hydrogel; covalent; pure zwitterionic ... See more keywords

Harnessing Non‐Covalent Protein–Protein Interaction Domains for Production of Biocatalytic Materials Systems

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Published in 2025 at "Advanced Functional Materials"

DOI: 10.1002/adfm.202513931

Abstract: Industrial biocatalysis has the potential to enable sustainable and environmentally friendly processes in the chemical industry. In continuous production systems, immobilized enzymes are required as catalysts, and providing them in a carrier‐free form is preferable… read more here.

Keywords: covalent; interaction domains; protein interaction; covalent protein ... See more keywords
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Molecular Engineering of Covalent Organic Framework Cathodes for Enhanced Zinc-Ion Batteries.

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Published in 2021 at "Advanced materials"

DOI: 10.1002/adma.202103617

Abstract: Covalent organic frameworks (COFs) are potentially promising electrode materials for electrochemical charge storage applications thanks to their pre-designable reticular chemistry with atomic precision, allowing precise control of pore size, redox-active functional moieties, and stable covalent… read more here.

Keywords: covalent; ion batteries; molecular engineering; zinc ion ... See more keywords

Stepwise On-Surface Synthesis and Transformations of Two-Dimensional Covalent Organic Frameworks by Controlled Thermal Stimuli.

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Published in 2025 at "Advanced materials"

DOI: 10.1002/adma.202506942

Abstract: The development of covalent organic frameworks (COFs) is currently a primary objective in materials science, taking into account the envisioned applications in a variety of fields, including gas and energy storage, sensing, catalysis, and optoelectronics.… read more here.

Keywords: covalent; covalent organic; thermal stimuli; surface ... See more keywords

Laser‐Induced Covalent Defunctionalization of Graphene — Precise Patterning and Site‐Selective Removal of Functional Groups

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Published in 2025 at "Advanced Science"

DOI: 10.1002/advs.202511481

Abstract: In this study, for the first time, site‐selective defunctionalization concepts for structuring and reusing covalently patterned monolayer graphene are reported. Using a laser‐activated precursor deposition approach with dibenzoyl peroxide (DBPO), phenyl moieties are covalently grafted… read more here.

Keywords: laser; defunctionalization; covalent; site selective ... See more keywords

Covalent Immobilization of β‐Glucosidase on Magnetic Spent Coffee Grounds Modified With PAMAM Dendrimers for Enhanced Glucose Tolerance

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Published in 2025 at "Biotechnology Journal"

DOI: 10.1002/biot.70025

Abstract: The successful application of enzymes in industries encounters challenges related to high costs, stability, and reuse. In this study, β‐glucosidase (BGL) was immobilized via a covalent method after the synthesis of different generations (G0‐2) of… read more here.

Keywords: covalent; pamam dendrimers; coffee grounds; spent coffee ... See more keywords

Flavin‐N5 Covalent Intermediate in a Nonredox Dehalogenation Reaction Catalyzed by an Atypical Flavoenzyme

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Published in 2018 at "ChemBioChem"

DOI: 10.1002/cbic.201700594

Abstract: The flavin‐dependent enzyme 2‐haloacrylate hydratase (2‐HAH) catalyzes the conversion of 2‐chloroacrylate, a major component in the manufacture of acrylic polymers, to pyruvate. The enzyme was expressed in Escherichia coli, purified, and characterized. 2‐HAH was shown… read more here.

Keywords: flavoenzyme; flavin covalent; covalent; flavin ... See more keywords

Serendipitous Identification of a Covalent Activator of Liver Pyruvate Kinase

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Published in 2022 at "Chembiochem"

DOI: 10.1002/cbic.202200339

Abstract: Enzymes are effective biological catalysts that accelerate almost all metabolic reactions in living organisms. Synthetic modulators of enzymes are useful tools for the study of enzymatic reactions and can provide starting points for the design… read more here.

Keywords: liver pyruvate; covalent; pyruvate kinase;

Covalent Modification of Bromodomain Proteins by Peptides Containing a DNA Damage‐Induced, Histone Post‐Translational Modification

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Published in 2022 at "ChemBioChem"

DOI: 10.1002/cbic.202200373

Abstract: An electrophilic 5‐methylene‐2‐pyrrolone modification (KMP) is produced at lysine residues of histone proteins in nucleosome core particles upon reaction with a commonly formed DNA lesion (C4‐AP). The nonenzymatic KMP modification is also generated in the… read more here.

Keywords: modification; histone; kmp; bromodomain ... See more keywords

Palladium Nanoparticles Stabilized by Metal–Carbon Covalent Bonds as an Expeditious Catalyst for the Oxidative Dehydrogenation of Nitrogen Heterocycles

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Published in 2017 at "ChemCatChem"

DOI: 10.1002/cctc.201700370

Abstract: The first method for the dehydrogenation of nitrogen heterocycles catalyzed by a palladium nanocatalyst was developed. Carbon–metal covalent‐bond‐stabilized nanoparticles were found to be efficient for the dehydrogenation process in the presence of tert‐butyl hydroperoxide. A… read more here.

Keywords: dehydrogenation nitrogen; carbon; dehydrogenation; nitrogen heterocycles ... See more keywords