Molecular Engineering of Covalent Organic Framework Cathodes for Enhanced Zinc-Ion Batteries.
Sign Up to like & getrecommendations! Published in 2021 at "Advanced materials"
DOI: 10.1002/adma.202103617
Abstract: Covalent organic frameworks (COFs) are potentially promising electrode materials for electrochemical charge storage applications thanks to their pre-designable reticular chemistry with atomic precision, allowing precise control of pore size, redox-active functional moieties, and stable covalent… read more here.
Keywords: covalent; ion batteries; molecular engineering; zinc ion ... See more keywords
Flavin‐N5 Covalent Intermediate in a Nonredox Dehalogenation Reaction Catalyzed by an Atypical Flavoenzyme
Sign Up to like & getrecommendations! Published in 2018 at "ChemBioChem"
DOI: 10.1002/cbic.201700594
Abstract: The flavin‐dependent enzyme 2‐haloacrylate hydratase (2‐HAH) catalyzes the conversion of 2‐chloroacrylate, a major component in the manufacture of acrylic polymers, to pyruvate. The enzyme was expressed in Escherichia coli, purified, and characterized. 2‐HAH was shown… read more here.
Keywords: flavoenzyme; flavin covalent; covalent; flavin ... See more keywords
Serendipitous Identification of a Covalent Activator of Liver Pyruvate Kinase
Sign Up to like & getrecommendations! Published in 2022 at "Chembiochem"
DOI: 10.1002/cbic.202200339
Abstract: Enzymes are effective biological catalysts that accelerate almost all metabolic reactions in living organisms. Synthetic modulators of enzymes are useful tools for the study of enzymatic reactions and can provide starting points for the design… read more here.
Keywords: liver pyruvate; covalent; pyruvate kinase;
Covalent Modification of Bromodomain Proteins by Peptides Containing a DNA Damage‐Induced, Histone Post‐Translational Modification
Sign Up to like & getrecommendations! Published in 2022 at "ChemBioChem"
DOI: 10.1002/cbic.202200373
Abstract: An electrophilic 5‐methylene‐2‐pyrrolone modification (KMP) is produced at lysine residues of histone proteins in nucleosome core particles upon reaction with a commonly formed DNA lesion (C4‐AP). The nonenzymatic KMP modification is also generated in the… read more here.
Keywords: modification; histone; kmp; bromodomain ... See more keywords
Palladium Nanoparticles Stabilized by Metal–Carbon Covalent Bonds as an Expeditious Catalyst for the Oxidative Dehydrogenation of Nitrogen Heterocycles
Sign Up to like & getrecommendations! Published in 2017 at "ChemCatChem"
DOI: 10.1002/cctc.201700370
Abstract: The first method for the dehydrogenation of nitrogen heterocycles catalyzed by a palladium nanocatalyst was developed. Carbon–metal covalent‐bond‐stabilized nanoparticles were found to be efficient for the dehydrogenation process in the presence of tert‐butyl hydroperoxide. A… read more here.
Keywords: dehydrogenation nitrogen; carbon; dehydrogenation; nitrogen heterocycles ... See more keywords
Covalent allosteric inhibitors of Akt generated using a click fragment approach.
Sign Up to like & getrecommendations! Published in 2022 at "ChemMedChem"
DOI: 10.1002/cmdc.202100776
Abstract: Akt is a protein kinase that has been implicated in the progression of cancerous tumors. A number of covalent allosteric Akt inhibitors are known, and based on these scaffolds, a small library of novel potential… read more here.
Keywords: covalent; allosteric inhibitors; covalent allosteric; inhibitors akt ... See more keywords
A Critical Study on Acylating and Covalent Reversible Fragment Inhibitors of SARS‐CoV‐2 Main Protease Targeting the S1 Site with Pyridine
Sign Up to like & getrecommendations! Published in 2023 at "ChemMedChem"
DOI: 10.1002/cmdc.202200635
Abstract: SARS coronavirus main proteases (3CL proteases) have been validated as pharmacological targets for the treatment of coronavirus infections. Current inhibitors of SARS main protease, including the clinically admitted drug nirmatrelvir are peptidomimetics with the downsides… read more here.
Keywords: inhibitors sars; main protease; covalent; site ... See more keywords
Covalent Grafting of a Nickel Thiolate Catalyst onto Covalent Organic Frameworks for Increased Photocatalytic Activity.
Sign Up to like & getrecommendations! Published in 2022 at "ChemSusChem"
DOI: 10.1002/cssc.202201943
Abstract: Covalent organic frameworks (COFs) have recently emerged as prospective photoactive materials with noble Pt as a cocatalyst for photocatalytic hydrogen evolution. In this work, a series of SH-group-functionalized covalent organic frameworks, TpPa-1-SH-X, is prepared by… read more here.
Keywords: organic frameworks; nickel thiolate; covalent grafting; covalent ... See more keywords
Mimicking Enzymatic Non-Covalent Interactions with Functionalized Covalent Organic Frameworks for Improved Adsorption and Hydrolysis of Cellobiose.
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200724
Abstract: Tunning catalytic centers in heterogeneous catalyst, both in a chemical and a spatial manner, is a powerful approach to improve the stability and the efficiency of catalysts. While the chemical aspects are largely understood, the… read more here.
Keywords: organic frameworks; hydrolysis cellobiose; non covalent; covalent ... See more keywords
Metal Coordination in Polyimine Covalent Adaptable Networks for Tunable Material Properties and Enhanced Creep Resistance.
Sign Up to like & getrecommendations! Published in 2023 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200790
Abstract: Covalent adaptable networks (CANs) have the potential to replace classical thermosets, as their unique dynamic-covalent bonds enable reprocessing and recycling of crosslinked polymers. A challenge for CANs remains their creep susceptibility, which hampers their application.… read more here.
Keywords: metal coordination; coordination; covalent; material properties ... See more keywords
Covalent Microporous Polymer Nanosheets for Efficient Photocatalytic CO2 Conversion with H2 O.
Sign Up to like & getrecommendations! Published in 2022 at "Small"
DOI: 10.1002/smll.202201314
Abstract: It is still a challenging target to achieve photocatalytic CO2 conversion to valuable chemicals with H2 O as an electron donor. Herein, 2D imide-based covalent organic polymer nanosheets (CoPcPDA-CMP NSs), which integrate cobalt phthalocyanine (CoPc)… read more here.
Keywords: co2 conversion; covalent; co2; photocatalytic co2 ... See more keywords