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Flavin‐N5 Covalent Intermediate in a Nonredox Dehalogenation Reaction Catalyzed by an Atypical Flavoenzyme

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Published in 2018 at "ChemBioChem"

DOI: 10.1002/cbic.201700594

Abstract: The flavin‐dependent enzyme 2‐haloacrylate hydratase (2‐HAH) catalyzes the conversion of 2‐chloroacrylate, a major component in the manufacture of acrylic polymers, to pyruvate. The enzyme was expressed in Escherichia coli, purified, and characterized. 2‐HAH was shown… read more here.

Keywords: flavoenzyme; flavin covalent; covalent; flavin ... See more keywords