Early-Transition-Metal Complexes of Functionalized Nonagermanide Clusters: Synthesis and Characterization of [Cp2(MeCN)Ti(η1-Ge9{Si(TMS)3}3)] and K3[Cp2Ti(η1-Ge9{Si(TMS)3}2)2].
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DOI: 10.1021/acs.inorgchem.9b02158
Abstract: Anionic clusters with a homoatomic [Ge9] core are species with Ge atoms in low oxidation states. In this study their reaction with early-transition-metal complexes was investigated. We report the syntheses of Ti(III) complexes of silylated… read more here.
Keywords: ge9 tms; transition metal; early transition; ge9 ... See more keywords