Unexpected differences in the reactivity between the phosphorus and arsenic derivatives [(CpBIGFe)2(μ,η4:4-E4)] (E = P and As).
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DOI: 10.1039/c7cc09730a
Abstract: Different reaction pathways were determined between thermolysis and photolysis reactions of the butterfly complex [{CpBIGFe(CO)2}2(μ,η1:1-As4)] (1b). The thermolysis leads to novel arsenic-rich compounds [(CpBIGFe)2(μ,η4:4-As4)] (2b), [(CpBIGFe)3(μ3,η4:4:4-As6)] (4) and [CpBIGFe(η5-As5)] (5), whereas the photolysis of [{CpBIGFe(CO)2}2(μ,η1:1-E4)]… read more here.
Keywords: reactivity phosphorus; differences reactivity; phosphorus arsenic; cpbigfe as4 ... See more keywords