CpNiBr(NHC) complexes as pre-catalysts in the chemoselective anaerobic oxidation of secondary aryl alcohols: Experimental and DFT studies
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DOI: 10.1016/j.mcat.2016.12.023
Abstract: Abstract Nine Ni(II)-NHC complexes of the type [CpNiBr(NHC)], each containing either a symmetric or asymmetric alkyl/benzyl/phenylethyl imidazolium ligand, effectively catalysed the anaerobic oxidation of a series of secondary alcohols, including 1-phenylethanol to yield acetophenone. Catalytic… read more here.
Keywords: secondary alcohols; nhc complexes; anaerobic oxidation; cpnibr nhc ... See more keywords