Molybdenum Trihydride Complexes: Computational Model of Oxidatively Induced Reductive Elimination of Dihydrogen.
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DOI: 10.1021/acs.inorgchem.6b02805
Abstract: Recent experimental work shows that the 18-electron molybdenum complexes (1,2,4-C5H2tBu3)Mo(PMe3)2H3 (CptBuMoH3) and (C5HiPr4)Mo(PMe3)2H3 (CpiPrMoH3) undergo oxidatively induced reductive elimination of dihydrogen (H2), slowly forming the 15-electron monohydride species in tetrahydrofuran and acetonitrile. The 17-electron [CptBuMoH3]+… read more here.
Keywords: induced reductive; oxidatively induced; cptbumoh3; cpiprmoh3 ... See more keywords