Creation of MOFs with open metal sites by partial replacement of metal ions with different coordination numbers.
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DOI: 10.1039/c8dt04218g
Abstract: Herein, we developed isostructural metal-organic frameworks (MOFs) [Cu1-xPdx(SiF6)(bpy)2] (bpy: 4,4'-bipyridine) (SIFSIX-1-CuPd-3, -5 and -10) containing open metal sites using a partial metal-replacement approach. Starting from the SIFSIX-1-Cu-type MOF, some of the Cu2+ ions having octahedral… read more here.
Keywords: replacement; open metal; metal; geometry ... See more keywords