Catalytic membrane reactor for Suzuki‐Miyaura C‐C cross‐coupling: Explanation for its high efficiency via modeling
Sign Up to like & getrecommendations! Published in 2017 at "Aiche Journal"
DOI: 10.1002/aic.15379
Abstract: A polymeric catalytic membrane was previously prepared that showed remarkable efficiency for Suzuki-Miyaura C-C cross-coupling in a flow-through configuration. A mathematic model was developed and fitted to the experimental data to understand the significant apparent… read more here.
Keywords: membrane reactor; miyaura cross; catalytic membrane; suzuki miyaura ... See more keywords
Microwave‐Promoted Metal‐Free α‐Alkylation of Ketones with Cycloalkanes through Cross‐Coupling of C(sp3)−H Bonds
Sign Up to like & getrecommendations! Published in 2017 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.201700256
Abstract: A MWI-promoted α-alkylation of ketones by using cycloalkanes as the alkylating agents under metal-free conditions is presented. Mechanistically, this alkylation involves a TBP-initiated and MWI-assisted formation of the required cycloalkyl radical and the α-ketone carbon… read more here.
Keywords: coupling sp3; sp3 bonds; alkylation; metal free ... See more keywords
Palladium‐Catalyzed Dehydrogenative Cross‐Coupling Reactions of Hydrosilanes: Facile Synthesis of Silanols and Silyl Ethers
Sign Up to like & getrecommendations! Published in 2024 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.202400471
Abstract: We present an efficient palladium‐catalyzed strategy that ingeniously realizes dehydrogenative cross‐coupling reactions between silanes and an oxygen‐containing functional groups (alcohols, phenols, and water) to generate the corresponding silyl ethers and silanols in moderate to high… read more here.
Keywords: dehydrogenative cross; cross coupling; palladium catalyzed; coupling reactions ... See more keywords
Electrochemical Cross‐Coupling Reactions
Sign Up to like & getrecommendations! Published in 2025 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.202500324
Abstract: The last few decades have seen an increase in the significance of green and sustainable synthetic processes for the synthesis of fine chemicals in an attempt to minimize the consumption of fossil fuels and other… read more here.
Keywords: chemistry; cross coupling; electrochemical cross; coupling reactions ... See more keywords
Transition Metal‐Free P‐Se Oxidative Cross‐Coupling for the Synthesis of Phosphoroselenothioates and Phosphoroselenoates
Sign Up to like & getrecommendations! Published in 2025 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.70223
Abstract: We report a one‐pot, transition metal‐free oxidative P‐Se cross‐coupling reaction for the synthesis of Se‐phosphoroselenothioates/phosphoroselenoates under ambient conditions. The reaction between phosphonothioates/phosphonates and diaryl diselenides proceeds efficiently within 3 h in acetonitrile under an oxygen… read more here.
Keywords: transition metal; cross coupling; metal free; oxidative cross ... See more keywords
Hiyama cross‐coupling reaction using Pd(II) nanocatalyst immobilized on the surface of Fe3O4@SiO2
Sign Up to like & getrecommendations! Published in 2018 at "Applied Organometallic Chemistry"
DOI: 10.1002/aoc.3978
Abstract: We report a simple process for the synthesis of Fe3O4@SiO2/APTMS (APTMS = 3-aminopropyltrimethoxysilane) core–shell nanocatalyst support. The new nanocatalyst was prepared by stabilization of Pd(cdha)2 (cdha = bis(2-chloro-3,4-dihydroxyacetophenone)) on the surface of the Fe3O4@SiO2/APTMS support. The structure and composition… read more here.
Keywords: surface fe3o4; fe3o4 sio2; sio2; hiyama cross ... See more keywords
Recent Updates on Pd‐Incorporated Ionic Liquids Catalyzed Suzuki Cross‐Coupling Reaction: A Mini‐Review
Sign Up to like & getrecommendations! Published in 2024 at "Applied Organometallic Chemistry"
DOI: 10.1002/aoc.7819
Abstract: Ionic liquids (ILs) have been recognized for their potential as environmentally friendly solvents when compared to traditional organic solvents. Additionally, their function goes beyond that of solvents, and cocatalysts, as they frequently act as stabilizing… read more here.
Keywords: reaction; recent updates; cross coupling; review ... See more keywords
Perfect Partners: Biocatalytic Halogenation and Metal Catalysis for Protein Bioconjugation
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DOI: 10.1002/cbic.202400496
Abstract: Flavin‐dependent halogenases (FDHs) are the most extensively researched halogenases and show great potential for biotransformation applications. These enzymes use chloride, bromide, or iodide ions as halogen donors to catalyze the oxygen‐dependent halogenation of electron‐rich aryl… read more here.
Keywords: cross coupling; biocatalytic halogenation; halogenation; protein ... See more keywords
Data Mining the C−C Cross‐Coupling Genome
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DOI: 10.1002/cctc.201900597
Abstract: The speed and precision of machine‐learning (ML) techniques in determining quantum chemical properties has resulted in a considerable computational speed up in comparison to traditional quantum chemical methods, and now allows a desired property of… read more here.
Keywords: quantum chemical; chemical properties; coupling genome; cross ... See more keywords
Cross‐Coupling Reaction of Alkyl Halides with Aldehydes through NHC Catalysis
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DOI: 10.1002/cctc.202400063
Abstract: During the past decades, N‐heterocyclic carbene (NHC)‐catalyzed reactions have emerged as a versatile tool in synthetic chemistry. In particular, NHC‐catalyzed cross‐coupling reaction has been significantly developed in many respects, including new reaction development and mechanistic… read more here.
Keywords: cross coupling; coupling reaction; alkyl halides; reaction alkyl ... See more keywords
Heterogeneous Electrocatalysts for Electrochemical Cross‐Coupling Reactions
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DOI: 10.1002/cctc.202401491
Abstract: Electro‐organic synthesis, a method that uses electrical current to drive various organic transformations, has garnered significant attention, and so has heterogeneous electrosynthesis, a process that produces chemicals through electrochemical reactions at the interface between the… read more here.
Keywords: cross coupling; electrochemical cross; coupling reactions; heterogeneous electrocatalysts ... See more keywords