Radical-Polar Crossover Enabled Photoredox 1,2-Carbosulfinylation of Alkenes with N-Sulfinyltritylamine.
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DOI: 10.1021/acs.orglett.5c04649
Abstract: The alkylation of N-sulfinylamines has emerged as a straightforward and promising platform for the construction of sulfinamides. Nevertheless, extant strategies─whether through two-electron nucleophilic addition or single-electron radical pathways─remain confined to two-component reactions, exhibiting intrinsic constraints… read more here.
Keywords: polar crossover; radical polar; photoredox carbosulfinylation; crossover enabled ... See more keywords