Study of spin crossover in an iron(II) tris(diimine) system tuned by counter anions
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DOI: 10.1016/j.poly.2016.09.059
Abstract: Abstract Investigations of spin-crossover in an iron(II) tris(diimine) system, based on the ligands L1 (4,5-dimethy-2-(pyridine-2-yl)imidazole) and L2 (1-acetic ethyl-2-(pyridine-2-yl)-imidazole), have been presented in this paper. The methyl groups at adjacent sites to the donor atoms… read more here.
Keywords: iron tris; spin crossover; crossover iron; counter anions ... See more keywords
Spin-crossover in an iron(III) complex showing a broad thermal hysteresis.
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DOI: 10.1039/d0dt03610b
Abstract: A pentadentate Schiff-base ligand 3,5Cl-L2- and NCSe- form an iron(iii) mononuclear complex, namely [Fe(3,5Cl-L)(NCSe)], which shows a thermally induced spin crossover with a broad hysteresis width of 24 K between 123 K (warming) and 99… read more here.
Keywords: complex showing; spin crossover; hysteresis; crossover iron ... See more keywords