A Rotorlike Supramolecular Assembly, {[K(18-crown-6)]PbI3}∞, with a Reversible Breaking-Symmetry Phase Transition near Room Temperature.
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DOI: 10.1021/acs.inorgchem.9b03517
Abstract: A rotorlike supramolecular crystal, {[K(18-crown-6)]PbI3}∞, is composed of a linear [PbI3]∞ chain acting as a stator and [K(18-crown-6)]+ cations fastened to the [PbI3]∞ chain and K-I bond like rotators and axes, respectively. A reversible breaking-symmetry… read more here.
Keywords: pbi3; reversible breaking; symmetry phase; rotorlike supramolecular ... See more keywords