Articles with "crystal engineering" as a keyword



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Implementing Logic Gates by DNA Crystal Engineering.

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Published in 2023 at "Advanced materials"

DOI: 10.1002/adma.202302345

Abstract: DNA self-assembly computation is attractive for its potential to perform massively parallel information processing at the molecular level while at the same time maintaining its natural biocompatibility. It has been extensively studied at the individual… read more here.

Keywords: logic gates; gates dna; crystal engineering; dna crystal ... See more keywords
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The "Chemistree" of Porous Coordination Networks: Taxonomic Classification of Porous Solids to Guide Crystal Engineering Studies.

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Published in 2021 at "Small"

DOI: 10.1002/smll.202006351

Abstract: New approaches to gas/vapor storage and purification are urgently needed to address the large energy footprint, cost, and/or risk associated with existing technologies. In this context, new classes of porous physisorbents, exemplified by porous coordination… read more here.

Keywords: taxonomic classification; classification; crystal engineering; coordination networks ... See more keywords
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Crystal engineering of versatile Hg(II) halides complexes of N,N,N′,N′-tetraalkyl substituted 3,5 pyridinedicarboxamides

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Published in 2018 at "Journal of Molecular Structure"

DOI: 10.1016/j.molstruc.2017.10.015

Abstract: Abstract Two new ligands N,N,N′,N′-tetraisopropyl/butyl-3,5-pyridinedicarboxamide ( L3-L4) and six of their Hg(II)X 2 complexes (where X = Cl − , Br − and I − ), have been synthesized and characterized using single crystal X-ray diffraction and… read more here.

Keywords: complexes tetraalkyl; crystal engineering; versatile halides; halides complexes ... See more keywords
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Crystal engineering and electrostatic properties of co-crystals of pyrimethamine with benzoic acid and gallic acid

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Published in 2020 at "Journal of Molecular Structure"

DOI: 10.1016/j.molstruc.2020.128183

Abstract: Abstract Crystal structures of co-crystal salt forms of anti-malarial drug pyrimethamine with benzoic acid in water solvent (I) and gallic acid in ethanol solvent (II) have been studied using X-ray diffraction data collected at room… read more here.

Keywords: electrostatic properties; crystal engineering; gallic acid; benzoic acid ... See more keywords
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Crystal Engineering and Photomagnetic Studies of CN-Bridged Coordination Polymers Based on Octacyanidometallates(IV) and [Ni(cyclam)]2+

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Published in 2022 at "Inorganic Chemistry"

DOI: 10.1021/acs.inorgchem.2c01629

Abstract: A series of new CN-bridged coordination networks of different dimensionality and topology was obtained through the modification of reaction conditions between [Ni(cyclam)]2+ (cyclam = 1,4,8,11-tetraazacyclotetradecane) and [W(CN)8]4–. The factors determining the reaction pathway are temperature… read more here.

Keywords: network; coordination; bridged coordination; li2 cyclam ... See more keywords
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Influence of Solvent in Crystal Engineering: A Significant Change to the Order-Disorder Transition in Ferrocene.

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Published in 2020 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.9b11895

Abstract: We present the structure of a novel solvate adduct formed by dissolving ferrocene, FeCp2, in hexafluorobenzene, C6F6. This adduct demonstrates the remarkably strong interactions between the five-membered aromatic rings of FeCp2 and the six-membered aromatic… read more here.

Keywords: crystal engineering; ferrocene; change; order disorder ... See more keywords
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Colloidal crystal engineering with metal–organic framework nanoparticles and DNA

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Published in 2020 at "Nature Communications"

DOI: 10.1038/s41467-020-16339-w

Abstract: Colloidal crystal engineering with nucleic acid-modified nanoparticles is a powerful way for preparing 3D superlattices, which may be useful in many areas, including catalysis, sensing, and photonics. To date, the building blocks studied have been… read more here.

Keywords: crystal engineering; metal organic; framework nanoparticles; colloidal crystal ... See more keywords
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Two-dimensional crystal engineering using halogen and hydrogen bonds: towards structural landscapes† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc00129k Click here for additional data file.

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Published in 2017 at "Chemical Science"

DOI: 10.1039/c7sc00129k

Abstract: We apply the concepts of supramolecular synthons and structural landscapes to 2D crystallization at the solution–solid interface. read more here.

Keywords: crystal engineering; engineering using; two dimensional; dimensional crystal ... See more keywords
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Tuning of the degree of charge transfer and the electronic properties in organic binary compounds by crystal engineering: a perspective

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Published in 2018 at "Journal of Materials Chemistry C"

DOI: 10.1039/c7tc04982j

Abstract: Organic charge-transfer compounds have received significant attention because of their tunable electronic properties, ranging from insulators to superconductors. It has been demonstrated that these compounds can be applied to both organic semiconducting active materials and… read more here.

Keywords: crystal engineering; degree charge; charge; electronic properties ... See more keywords
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Investigating the Crystal Engineering of the Pillared Paddlewheel Metal-Organic Framework Zn2(NH2BDC)2DABCO

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Published in 2018 at "CrystEngComm"

DOI: 10.1039/c8ce00848e

Abstract: The synthesis of Zn2(NH2BDC)2DABCO was investigated with the hopes of producing a material with a high surface area. Despite considerable efforts to get reproducible results, replacing BDC with NH2BDC was not trivial; the gas adsorption… read more here.

Keywords: engineering pillared; crystal engineering; nh2bdc 2dabco; investigating crystal ... See more keywords
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Halogenated building blocks for 2D crystal engineering on solid surfaces: lessons from hydrogen bonding† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc04499f

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Published in 2019 at "Chemical Science"

DOI: 10.1039/c8sc04499f

Abstract: We test whether the similarities between halogen and hydrogen bonds could be used to design a surface-confined halogen-bond based network. read more here.

Keywords: crystal engineering; building blocks; halogenated building; solid surfaces ... See more keywords