Photodriven single-crystal-to-single-crystal transformation
Sign Up to like & getrecommendations! Published in 2017 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2016.06.009
Abstract: Abstract Molecular architectures containing photosensitive units respond to light, giving dramatic variations of their structure. In particular, the crystalline packing phases offer the possibility of significant advances in crystal design and the understanding of solid-state… read more here.
Keywords: crystal single; single crystal; chemistry; photodriven single ... See more keywords
Direct formation of [NH4]N3 from a pentazolate salt through single-crystal to single-crystal transformation
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2018.02.001
Abstract: Abstract In the area of polynitrogen anions, the only stable species synthesized as yet are the azide anion (N3−) and the pentazolate anion (cyclo-N5−). We here describe an unprecedented example of a spontaneous single-crystal to… read more here.
Keywords: crystal single; single crystal; crystal transformation; pentazolate ... See more keywords
Single-crystal-to-single-crystal mediated metal exchange from Zn(II) to Cu(II) and diverse structures in Zn/Cu coordination polymers using pyridylmethionine ligand
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2020.129527
Abstract: Abstract A reaction of 2-((pyridin-4-yl)methylamino)-4-(methylthio)butanoic acid (HL) and Zn(OAc)2.2H2O afforded a hexacoodinated coordination polymer of [Zn(L)(HL)(H2O)2]n (Zn-1). When the single crystals of Zn-1, are suspended in water-DMF (2:1) solution of Cu(OAc)2.H2O, a quantitative metal exchange… read more here.
Keywords: crystal single; single crystal; coordination; metal exchange ... See more keywords
Single-Crystal-to-Single-Crystal Transformation of Two Copper(II) Metal-Organic Frameworks Modulated by Auxiliary Ligands.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c02854
Abstract: The single-crystal-to-single-crystal (SCSC) transformations of metal-organic frameworks (MOFs) are fascinating because we can directly observe the change of the crystal structure during the transformation process. It also greatly helps to understand the delicate interaction between… read more here.
Keywords: single crystal; organic frameworks; crystal single; metal organic ... See more keywords
Reversible Single-Crystal-to-Single-Crystal Transformation of a Coordination Polymer through Solar-Switchable Cycloaddition and Cycloreversion Reaction.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03188
Abstract: Reversible covalent reactions within crystalline complexes are powerful tools for the design and developing of new generation of reusable smart materials. In this work, a unique photoreactive olefin-containing metal-organic coordination polymer [Ag2(2,3-ppe)2(1,3-bdc)]n (1) was prepared… read more here.
Keywords: single crystal; coordination polymer; reaction; crystal single ... See more keywords
A 3D Calcium Spirobifluorene Metal-Organic Framework: Single-Crystal-to-Single-Crystal Transformation and Toluene Detection by a Quartz Crystal Microbalance Sensor.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b02671
Abstract: A new 3D metal-organic framework Ca-SBF based on a zigzag-shaped tetranuclear calcium oxocluster and 9,9'-spirobi[9H-fluorene]-2,2',7,7'-tetracarboxylic acid was obtained and exhibited flu topology. Ca-SBF underwent a single-crystal-to-single-crystal transformation to form Ca-SBF-1 with a slight structure shrinkage.… read more here.
Keywords: quartz crystal; single crystal; metal organic; crystal single ... See more keywords
Thermostructural Behavior in a Series of Lanthanide-Containing Polyoxotungstate Hybrids with Copper(II) Complexes of the Tetraazamacrocycle Cyclam: A Single-Crystal-to-Single-Crystal Transformation Study.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b03471
Abstract: A series of 14 isostructural [Cu(cyclam)]2[{Cu(cyclam)}4{(α-GeW11O39)Ln(H2O)(OAc)}2]·18H2O (1-Ln, where Ln = La-Lu; cyclam = 1,4,8,11-tetraazacyclotetradecane) polyoxometalate-based hybrids reported herein represent (i) the first example of a two-dimensional covalent hybrid lattice involving the [{(α-XW11O39)Ln(H2O)(OAc)}2] n- archetype and… read more here.
Keywords: crystal single; cyclam; single crystal; thermostructural behavior ... See more keywords
Inverse Isotope Effects in Single-Crystal to Single-Crystal Reactivity and the Isolation of a Rhodium Cyclooctane σ-Alkane Complex
Sign Up to like & getrecommendations! Published in 2022 at "Organometallics"
DOI: 10.1021/acs.organomet.1c00639
Abstract: The sequential solid/gas single-crystal to single-crystal reaction of [Rh(Cy2P(CH2)3PCy2)(COD)][BArF4] (COD = cyclooctadiene) with H2 or D2 was followed in situ by solid-state 31P{1H} NMR spectroscopy (SSNMR) and ex situ by solution quenching and GC-MS. This… read more here.
Keywords: single crystal; crystal single; inverse isotope; alkane complex ... See more keywords
Single-Crystal to Single-Crystal Transformation of Metal–Organic Framework Nanoparticles for Encapsulation and pH-Stimulated Release of Camptothecin
Sign Up to like & getrecommendations! Published in 2021 at "ACS Applied Nano Materials"
DOI: 10.1021/acsanm.1c01146
Abstract: The phenomenon of single-crystal to single-crystal transformation and the performance change along with the transformation have been widely discovered, whereas the efficient utilization of the crystal transformation process is less reported. Herein, we present an… read more here.
Keywords: encapsulation; single crystal; transformation; crystal single ... See more keywords
Rare Silver–Histidine Cluster Complex and Its Single-Crystal-to-Single-Crystal Phase-Transition Behavior
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c00094
Abstract: Silver complexes with proteinogenic amino acid ligands are of interest for biomedical and antimicrobial applications. In this work, we obtained {[Ag7(l-his)4](NO3)3·3H2O}0.2{[Ag8(l-his)4(H2O)2](NO3)4·3H2O}0.8 (1) and {[Ag7(d-his)4](NO3)3·3H2O}0.2{[Ag8(d-his)4(H2O)2](NO3)4·3H2O}0.8 (2), which represent the first example of any Ag-exclusive complex featuring… read more here.
Keywords: single crystal; no3 3h2o; silver; crystal single ... See more keywords
A new multitalented azine ligand: elastic bending, single-crystal-to-single-crystal transformation and a fluorescence turn-on Al(iii) sensor.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc04392a
Abstract: We report a rare combination of two unique properties of an azine based ligand (H3L): in a solid-state crystalline material it shows highly flexible and elastic behavior which on triggering with light results in slight… read more here.
Keywords: crystal single; single crystal; new multitalented; transformation ... See more keywords