Crystalline paramagnetic supramolecular 2D-polymer of the tetra(4-pyridyl)porphyrin and terbium(III) complex.
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DOI: 10.1039/d2dt03170a
Abstract: A new promising method for the preparation of crystalline 2D polymers based on tetra(4-pyridyl)porphyrin has been developed. Radical anion {H2T(4-Py)P˙-} species are used as the starting material. A new solid-state supramolecular array [{H2T(4-Py)P}·{TbIII(TMHD)3}2]·2.84C6H14 (1) in… read more here.
Keywords: pyridyl porphyrin; polymer; crystalline paramagnetic; tetra pyridyl ... See more keywords