Structure determination of terpenes by the crystalline sponge method
Sign Up to like & getrecommendations! Published in 2020 at "Microporous and Mesoporous Materials"
DOI: 10.1016/j.micromeso.2020.110548
Abstract: Abstract The crystalline sponge method was used to produce novel encapsulation complexes with the aim of structural determination of terpenes, such as geraniol-monoterpenoid, farnesol-sesquiterpenoid and β-damascone-tetraterpenoids. Along with the structure determination of the terpenoids, non-bonding… read more here.
Keywords: determination; sponge method; structure determination; crystalline sponge ... See more keywords
Solvent Effects in the Crystalline Sponge Method: Importance of Co-solvents for Ordering Absorbed Guests.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c03660
Abstract: In the crystalline sponge method, the crucial step for ordering the absorbed guest is soaking of the guest into the pores of the crystalline sponge. Here, we find that the choice of solvent is particularly… read more here.
Keywords: guest soaking; sponge; sponge method; ordering absorbed ... See more keywords
Crystalline Sponge Method Enabled the Investigation of a Prenyltransferase-terpene Synthase Chimeric Enzyme, Whose Product Exhibits Broadened NMR Signals.
Sign Up to like & getrecommendations! Published in 2018 at "Organic letters"
DOI: 10.1021/acs.orglett.8b02284
Abstract: By the genome-mining approach, a chimeric enzyme of prenyltransferase-diterpene synthase was discovered from Penicillium chrysogenum MT-12. Since its product exhibited broadened NMR signals, the structural determination by only the NMR analysis was difficult, but the… read more here.
Keywords: sponge method; crystalline sponge; chimeric enzyme; broadened nmr ... See more keywords
Single-molecule magnetism arising from cobalt(II) nodes of a crystalline sponge
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Materials Chemistry C"
DOI: 10.1039/c6tc04703c
Abstract: The remarkable Metal–Organic Framework (MOF), {[(Co(NCS)2)3(κ3-TPT)4]·a(H2O)·b(MeOH)}n (1), which is used in the revolutionary crystalline sponge method, displays characteristic Single-Molecule Magnet (SMM) behaviour under applied static fields. We report the subtle effects of changes in the… read more here.
Keywords: crystalline sponge; single molecule; tpt h2o; sponge ... See more keywords
Crystalline Sponge Method by Three-Dimensional Electron Diffraction
Sign Up to like & getrecommendations! Published in 2022 at "Frontiers in Molecular Biosciences"
DOI: 10.3389/fmolb.2021.821927
Abstract: The crystalline sponge method has shown to be a novel strategy for the structure determination of noncrystalline, oily, or trace amount of a compound. A target compound was absorbed and oriented orderly in the pregrown… read more here.
Keywords: crystalline sponge; diffraction; sponge method; sponge ... See more keywords
Highly Luminescent Crystalline Sponge: Sensing Properties and Direct X-ray Visualization of the Substrates
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27228055
Abstract: A phenomenon of crystalline sponge is represented by guest-dependent structural fluidity of the host polymeric lattice in highly crystalline sorbents, such as metal-organic frameworks, driven by multiple weak intermolecular interactions. Such induced fitting in MOFs… read more here.
Keywords: eu2; crystalline sponge; properties direct; sponge ... See more keywords