Single-Crystalline UiO-67-Type Porous Network Stable to Boiling Water, Solvent Loss, and Oxidation.
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DOI: 10.1021/acs.inorgchem.8b00404
Abstract: With methylthio groups flanking the carboxyl groups, the 3,3',5,5'-tetrakis(methylthio)biphenyl dicarboxylate (TMBPD) linker forms a zirconium(IV) carboxylate porous framework featuring the topology of the UiO-67 prototype, i.e., with a face-centered-cubic array of the Zr6O4(OH)4 clusters. Thioether… read more here.
Keywords: oxidation; water; uio type; single crystalline ... See more keywords