Multicompartment Nanoparticles by Crystallization-Driven Self-Assembly of Star Polymers: Combining High Stability and Loading Capacity.
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200706
Abstract: Herein we develop a novel multicompartment nanoparticles (MCNs) that combine high stability and cargo loading capacity. The MCNs were fabricated by crystallization-driven self-assembly (CDSA) of a tailor-made 21 arm star polymer, poly(L -lactide)[poly(tert-buty acrylate)-block-poly(ethylene glycol)]20… read more here.
Keywords: high stability; capacity; loading capacity; crystallization driven ... See more keywords
Effect of solvent selectivity on crystallization-driven fibril growth kinetics of diblock copolymers
Sign Up to like & getrecommendations! Published in 2018 at "Polymer"
DOI: 10.1016/j.polymer.2018.01.074
Abstract: Abstract We performed dynamic Monte Carlo simulations of diblock copolymers to investigate how the selective solvents on two blocks can suppress the crystallization-driven fibril self-assembly growth in dilute solutions. We found that either a lower… read more here.
Keywords: growth; crystallization; effect; driven fibril ... See more keywords
Concepts, fabrication methods and applications of living crystallization-driven self-assembly of block copolymers
Sign Up to like & getrecommendations! Published in 2020 at "Progress in Polymer Science"
DOI: 10.1016/j.progpolymsci.2019.101195
Abstract: Abstract Living crystallization-driven self-assembly (CDSA) has emerged as a technique that is able to perform solution phase self-assembly of semi-crystalline block copolymers in a controlled and modular fashion. It has been widely demonstrated to generate… read more here.
Keywords: driven self; self assembly; living crystallization; block copolymers ... See more keywords
(Bio)degradable and Biocompatible Nano-Objects from Polymerization-Induced and Crystallization-Driven Self-Assembly.
Sign Up to like & getrecommendations! Published in 2022 at "Biomacromolecules"
DOI: 10.1021/acs.biomac.2c00230
Abstract: Polymerization-induced self-assembly (PISA) and crystallization-driven self-assembly (CDSA) techniques have emerged as powerful approaches to produce a broad range of advanced synthetic nano-objects with high potential in biomedical applications. PISA produces nano-objects of different morphologies (e.g.,… read more here.
Keywords: polymerization induced; self assembly; nano objects; crystallization driven ... See more keywords
Solid-State Donor-Acceptor Coaxial Heterojunction Nanowires via Living Crystallization-Driven Self-Assembly.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c04975
Abstract: The creation of organic heterojunctions from conjugated polymers on the nanoscale has attracted recent attention as a consequence of their considerable potential in optoelectronic devices. Herein, we report proof-of-concept results on a versatile synthetic strategy… read more here.
Keywords: solid state; crystallization; living crystallization; crystallization driven ... See more keywords
Synchronous Preparation of Length-Controllable 1D Nanoparticles via Crystallization-Driven In Situ Nanoparticlization of Conjugated Polymers.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c13385
Abstract: Precise size control of semiconducting nanomaterials from polymers is crucial for optoelectronic applications, but the low solubility of conjugated polymers makes this challenging. Herein, we prepared length-controlled semiconducting one-dimensional (1D) nanoparticles by synchronous self-assembly during… read more here.
Keywords: driven situ; nanoparticlization conjugated; crystallization driven; situ nanoparticlization ... See more keywords
Scalable and Uniform Length-Tunable Biodegradable Block Copolymer Nanofibers with a Polycarbonate Core via Living Polymerization-Induced Crystallization-Driven Self-assembly.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c09715
Abstract: Uniform 1D block copolymer (BCP) nanofibers prepared by the seeded-growth approach termed living crystallization-driven self-assembly (CDSA) offer promising potential for various applications due to their anisotropy, length tunability, and variable core and coronal chemistries. However,… read more here.
Keywords: core; self assembly; block copolymer; crystallization driven ... See more keywords
Preparing Semiconducting Nanoribbons with Tunable Length and Width via Crystallization-Driven Self-Assembly of a Simple Conjugated Homopolymer.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b10406
Abstract: Precise control of width and length of one-dimensional (1D) semiconducting nanostructures has attracted much attention owing to its potential for optoelectronic applications. However, regulating both their length and width using conjugated polymers or even block… read more here.
Keywords: driven self; self assembly; via crystallization; crystallization driven ... See more keywords
Rapid formation and real-time observation of micron-sized conjugated nanofibers with tunable lengths and widths in 20 minutes by living crystallization-driven self-assembly†
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Science"
DOI: 10.1039/d0sc02891f
Abstract: Preparing well-defined semiconducting nanostructures from conjugated polymers is of paramount interest for organic optoelectronic devices. Several studies have demonstrated excellent structural and size control from block copolymers (BCPs) containing non-conjugated blocks via crystallization-driven self-assembly (CDSA);… read more here.
Keywords: driven self; self assembly; real time; micron sized ... See more keywords
π-Conjugated-polymer-based nanofibers through living crystallization-driven self-assembly: preparation, properties and applications.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc04825b
Abstract: π-Conjugated-polymer-based nanofibers (CPNFs) of controlled length, composition and morphology are promising for a broad range of emerging applications in optoelectronics, biomedicine and catalysis, owing to the morphological merits of fiber-like nanostructures and structural attributes of… read more here.
Keywords: based nanofibers; living crystallization; polymer; conjugated polymer ... See more keywords
The role of cooling rate in crystallization-driven block copolymer self-assembly
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DOI: 10.1039/d1sc05937h
Abstract: Self-assembly of crystalline-coil block copolymers (BCPs) in selective solvents is often carried out by heating the mixture until the sample appears to dissolve and then allowing the solution to cool back to room temperature. In… read more here.
Keywords: self assembly; cooling rate; self; crystallization driven ... See more keywords