Harnessing Crystallization‐Driven Self‐Assembly (CDSA) of Semicrystalline Block Copolymers for Functional 2D Architectures and Their Applications
Sign Up to like & getrecommendations! Published in 2025 at "Macromolecular Chemistry and Physics"
DOI: 10.1002/macp.202400426
Abstract: 2D micelles have attracted considerable attention in materials science due to their high surface area, tunable surface properties, and diverse potential applications. Although various methods are well‐established for synthesizing 2D inorganic materials, the development of… read more here.
Keywords: chemistry; driven self; assembly cdsa; self assembly ... See more keywords
Multicompartment Nanoparticles by Crystallization-Driven Self-Assembly of Star Polymers: Combining High Stability and Loading Capacity.
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200706
Abstract: Herein we develop a novel multicompartment nanoparticles (MCNs) that combine high stability and cargo loading capacity. The MCNs were fabricated by crystallization-driven self-assembly (CDSA) of a tailor-made 21 arm star polymer, poly(L -lactide)[poly(tert-buty acrylate)-block-poly(ethylene glycol)]20… read more here.
Keywords: high stability; capacity; loading capacity; crystallization driven ... See more keywords
Crystallization-Driven Controlled 2D Self-Assemblies via Aqueous RAFT Emulsion Polymerization.
Sign Up to like & getrecommendations! Published in 2024 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202400549
Abstract: Aqueous emulsion polymerization is a robust technique for preparing nanoparticles of block copolymers; however, it typically yields spherical nanoassemblies. The scale preparation of nanoassemblies with nonspherical high-order morphologies is a challenge, particularly 2D core-shell nanosheets.… read more here.
Keywords: raft emulsion; emulsion polymerization; polymerization; crystallization driven ... See more keywords
Effect of solvent selectivity on crystallization-driven fibril growth kinetics of diblock copolymers
Sign Up to like & getrecommendations! Published in 2018 at "Polymer"
DOI: 10.1016/j.polymer.2018.01.074
Abstract: Abstract We performed dynamic Monte Carlo simulations of diblock copolymers to investigate how the selective solvents on two blocks can suppress the crystallization-driven fibril self-assembly growth in dilute solutions. We found that either a lower… read more here.
Keywords: growth; crystallization; effect; driven fibril ... See more keywords
Concepts, fabrication methods and applications of living crystallization-driven self-assembly of block copolymers
Sign Up to like & getrecommendations! Published in 2020 at "Progress in Polymer Science"
DOI: 10.1016/j.progpolymsci.2019.101195
Abstract: Abstract Living crystallization-driven self-assembly (CDSA) has emerged as a technique that is able to perform solution phase self-assembly of semi-crystalline block copolymers in a controlled and modular fashion. It has been widely demonstrated to generate… read more here.
Keywords: driven self; self assembly; living crystallization; block copolymers ... See more keywords
(Bio)degradable and Biocompatible Nano-Objects from Polymerization-Induced and Crystallization-Driven Self-Assembly.
Sign Up to like & getrecommendations! Published in 2022 at "Biomacromolecules"
DOI: 10.1021/acs.biomac.2c00230
Abstract: Polymerization-induced self-assembly (PISA) and crystallization-driven self-assembly (CDSA) techniques have emerged as powerful approaches to produce a broad range of advanced synthetic nano-objects with high potential in biomedical applications. PISA produces nano-objects of different morphologies (e.g.,… read more here.
Keywords: polymerization induced; self assembly; nano objects; crystallization driven ... See more keywords
Solid-State Donor-Acceptor Coaxial Heterojunction Nanowires via Living Crystallization-Driven Self-Assembly.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c04975
Abstract: The creation of organic heterojunctions from conjugated polymers on the nanoscale has attracted recent attention as a consequence of their considerable potential in optoelectronic devices. Herein, we report proof-of-concept results on a versatile synthetic strategy… read more here.
Keywords: solid state; crystallization; living crystallization; crystallization driven ... See more keywords
Synchronous Preparation of Length-Controllable 1D Nanoparticles via Crystallization-Driven In Situ Nanoparticlization of Conjugated Polymers.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c13385
Abstract: Precise size control of semiconducting nanomaterials from polymers is crucial for optoelectronic applications, but the low solubility of conjugated polymers makes this challenging. Herein, we prepared length-controlled semiconducting one-dimensional (1D) nanoparticles by synchronous self-assembly during… read more here.
Keywords: driven situ; nanoparticlization conjugated; crystallization driven; situ nanoparticlization ... See more keywords
Scalable and Uniform Length-Tunable Biodegradable Block Copolymer Nanofibers with a Polycarbonate Core via Living Polymerization-Induced Crystallization-Driven Self-assembly.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c09715
Abstract: Uniform 1D block copolymer (BCP) nanofibers prepared by the seeded-growth approach termed living crystallization-driven self-assembly (CDSA) offer promising potential for various applications due to their anisotropy, length tunability, and variable core and coronal chemistries. However,… read more here.
Keywords: core; self assembly; block copolymer; crystallization driven ... See more keywords
Highly Efficient Preparation of Length and Width-Controllable Donor-Acceptor Nanoribbons via Polymerization-Induced Crystallization-Driven Self-Assembly of Fully Conjugated Block Copolymers.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c04039
Abstract: Despite the high potential of one-dimensional (1D) donor-acceptor (D-A) coaxial nanostructures in bulk-heterojunction solar cell applications, the preparation of such 1D nanostructures using π-conjugated polymers has remained elusive. Herein, we demonstrate the first example of… read more here.
Keywords: seed; driven self; highly efficient; polymerization ... See more keywords
Preparing Semiconducting Nanoribbons with Tunable Length and Width via Crystallization-Driven Self-Assembly of a Simple Conjugated Homopolymer.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b10406
Abstract: Precise control of width and length of one-dimensional (1D) semiconducting nanostructures has attracted much attention owing to its potential for optoelectronic applications. However, regulating both their length and width using conjugated polymers or even block… read more here.
Keywords: driven self; self assembly; via crystallization; crystallization driven ... See more keywords