Articles with "crystallographic characterization" as a keyword



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Crystallographic characterization of irradiated U-10Zr and U-10Zr-5Ce metallic fuels

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Published in 2017 at "Journal of Radioanalytical and Nuclear Chemistry"

DOI: 10.1007/s10967-017-5591-5

Abstract: Crystal structures of irradiated U-10Zr and U-10Zr-5Ce metallic fuels at approximately 2.9 at.% burnup were probed by micro-X-ray diffraction, which identified the presence of UO2 and α-U phases in both fuels. Analysis of the lattice… read more here.

Keywords: 10zr 10zr; metallic fuels; irradiated 10zr; crystallographic characterization ... See more keywords
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Nanoscale crystallographic characterization of nanoporous catalyst by TKD

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Published in 2019 at "Applied Surface Science"

DOI: 10.1016/j.apsusc.2019.05.187

Abstract: Abstract To better understand the structure-reactivity relationships of self-supported nanoporous catalysts, a nanoscale characterization of the materials is required. Transmission Kikuchi Diffraction (TKD), or transmission electron backscatter diffraction (t-EBSD), is a recent technique used to… read more here.

Keywords: characterization nanoporous; characterization; nanoporous catalyst; nanoscale crystallographic ... See more keywords
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Crystallographic characterization of Y2C2n (2n = 82, 88–94): direct Y–Y bonding and cage-dependent cluster evolution

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Published in 2019 at "Chemical Science"

DOI: 10.1039/c9sc00941h

Abstract: The long-sought Y–Y bonding is experimentally observed in organometallic complexes for the first time by encapsulation inside the hollow cavity of C3v(8)-C82 and Cs(6)-C82 fullerene cages. read more here.

Keywords: y2c2n direct; cage dependent; characterization y2c2n; direct bonding ... See more keywords
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Dy@D2(21)-C84: Isolation and crystallographic characterization of a rare trivalent C84-based monometallofullerene

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Published in 2023 at "Inorganic Chemistry Frontiers"

DOI: 10.1039/d3qi00469d

Abstract: Monometallofullerenes (mono-EMFs), which only contain one metal atom inside the fullerene cage, are the most basic yet crucial prototypes to understand the structures and characteristics of EMFs. However, although trivalent... read more here.

Keywords: c84; characterization rare; crystallographic characterization; c84 isolation ... See more keywords
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Clarifying the structures of imidines: using crystallographic characterization to identify tautomers and localized systems of π-bonding

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Published in 2023 at "Acta Crystallographica. Section C, Structural Chemistry"

DOI: 10.1107/s2053229623002036

Abstract: A combination of solid state, solution, and computational studies are employed to best describe the various possible tautomers of succinimidine and glutarimidine species and the corresponding hydrolyzed imino–imide compounds. read more here.

Keywords: using crystallographic; imidines using; crystallographic characterization; structures imidines ... See more keywords
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Crystallographic characterization of rare-earth cyanotriphenylborate complexes and the cyanoborates [NCBPh3]1−, [NCBPh2Me]1−, and [NCBPh2(μ-O)BPh2]1−

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Published in 2021 at "Acta Crystallographica Section E: Crystallographic Communications"

DOI: 10.1107/s2056989021006861

Abstract: The investigation of the coordination chemistry of rare-earth metal complexes with cyanide ligands led to the isolation and crystallographic characterization of the Ln III cyanotriphenylborate complexes, LnCl2(THF)4(NCBPh3) (Ln = Dy, Y) as well as the… read more here.

Keywords: cyanotriphenylborate complexes; bph2; ncbph2 bph2; rare earth ... See more keywords
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Synthesis and crystallographic characterization of a brominated porphyrin with a nitrophenyl substituent and its iron derivative

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Published in 2018 at "Journal of Porphyrins and Phthalocyanines"

DOI: 10.1142/s1088424618500578

Abstract: 2,3,7,8,12,13,17,18-Octabromo-5-(2-nitrophenyl)-10,15,20-triphenyl porphyrin (H2OBP-NO2) and its metallic complexes have been designed and synthesized. Both the free-base porphyrin and its iron(III... read more here.

Keywords: crystallographic characterization; porphyrin nitrophenyl; brominated porphyrin; synthesis crystallographic ... See more keywords