Crystallographic and Spectroscopic Characterization of Americium Complexes Containing the Bis[(phosphino)methyl]pyridine-1-oxide (NOPOPO) Ligand Platform.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b03154
Abstract: The crystal structures of americium species containing a common multifunctional phosphine oxide ligand, reported for its ability to extract f elements from acidic solutions, namely, 2,6-[Ph2P(O)CH2]2C5H3-NO, L, were finally determined after over three decades of… read more here.
Keywords: spectroscopic characterization; characterization americium; spectroscopy; ligand ... See more keywords
Synthesis, crystallographic and spectroscopic characterization, and theoretical elucidation of an elusive aminyl radical containing a CuII-aminyl-iminosemiquinone complex.
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DOI: 10.1039/d0cc07378d
Abstract: An elusive aminyl radical and an iminosemiquinone radical-coordinated square pyramidal Cu(ii) complex (1) have been isolated by the reaction between the noninnocent ligand H4LPy(AP) and Cu(ClO4)2ยท6H2O in the presence of Et3N and air as the… read more here.
Keywords: spectroscopic characterization; synthesis crystallographic; aminyl radical; elusive aminyl ... See more keywords
Crystallographic and spectroscopic assignment of the proton transfer pathway in [FeFe]-hydrogenases.
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DOI: 10.2210/pdb6gm1/pdb
Abstract: The unmatched catalytic turnover rates of [FeFe]-hydrogenases require an exceptionally efficient proton-transfer (PT) pathway to shuttle protons as substrates or products between bulk water and catalytic center. For clostridial [FeFe]-hydrogenase CpI such a pathway has… read more here.
Keywords: fefe hydrogenases; proton; proton transfer; transfer pathway ... See more keywords