CsHfF4(IO3): A Hafnium Iodate Exhibiting a Strong Second-Harmonic-Generation Effect and a Wide Band Gap Achieved by Mixed-Ligand Acentric Coordination.
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DOI: 10.1021/acs.inorgchem.3c00189
Abstract: A new polar hafnium iodate, CsHfF4(IO3), was successfully designed and synthesized by integrating fluorinated hafnium-oxygen polyhedra (HfF6O2) and IO3- anionic functional groups. Owing to the weak electronic effect of Hf4+ and the bond-network-induced out-of-center distortion… read more here.
Keywords: io3; cshff4 io3; effect; hafnium iodate ... See more keywords