Photoinduced Pd-Catalyzed Csp2-H/Csp3-H Dehydrocoupling Reaction Employing Polyhaloaromatics as the Dehydrogenating Agent.
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DOI: 10.1021/acs.orglett.2c03708
Abstract: A mild strategy for intermolecular cross-dehydrocoupling of Csp2-H bonds and Csp3-H bonds has been developed with the aid of photoinduced Pd catalysis. Polyhalogenated arenes can be used as the efficient dehydrogenating agent, which enables multifold… read more here.
Keywords: csp3 dehydrocoupling; photoinduced catalyzed; agent; csp2 csp3 ... See more keywords
Rh(iii)-Catalyzed Csp2–Csp3 bond alkoxylation of α-indolyl alcohols via C–C σ bond cleavage
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DOI: 10.1039/d1qo00194a
Abstract: A Rh(iii)-catalyzed direct Csp2–Csp3 bond alkoxylation of α-(2-indolyl)alcohols with alcohols has been achieved via C–C sigma bond/C–O single bond switch. read more here.
Keywords: bond alkoxylation; csp3 bond; alkoxylation indolyl; iii catalyzed ... See more keywords