Cationic Single-Unit Monomer Insertion (cSUMI): From Discrete Oligomers to the α-/ω-End and In-Chain Sequence-Regulated Polymers.
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DOI: 10.1021/jacs.2c12873
Abstract: Single-unit monomer insertion (SUMI) has become an important strategy for the synthesis of sequence-controlled vinyl polymers due to its strong versatility and high efficiency. However, all reported SUMI processes are based on a free-radical mechanism,… read more here.
Keywords: sequence; sequence regulated; csumi; single unit ... See more keywords