The First Copper(I)-Olefin Complexes Bearing a 1,3,4-Oxadiazole Core : Alternating-Current Electrochemical Crystallization, X-ray Experiment and DFT Study
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DOI: 10.1016/j.poly.2017.05.052
Abstract: Abstract By means of alternating-current electrochemical technique, four new π-complexes, namely [Cu2(C11H10N2OS)2Br1.91Cl0.09] (1), [Cu(C11H10N2OS)NO3] (2), [Cu2(C11H10N2OS)2(H2O)2](BF4)2 (3) and [Cu2(C11H10N2OS)2(H2O)2](ClO4)2 (4), were obtained using copper(II) salts and the 2-(allylthio)-5-phenyl-1,3,4-oxadiazole (C11H10N2OS) ligand. The metal and halogen centers… read more here.
Keywords: cu2 c11h10n2os; dft; c11h10n2os; current electrochemical ... See more keywords