CO2 and N2 adsorption and separation using aminated UiO-66 and Cu3(BTC)2: A comparative study
Sign Up to like & getrecommendations! Published in 2020 at "Korean Journal of Chemical Engineering"
DOI: 10.1007/s11814-019-0433-5
Abstract: UiO-66 and Cu3(BTC)2, two well-known metal organic frameworks (MOFs), were aminated through insitu modification approach to improve CO2/N2 separation. UiO-66 was synthesized by solvothermal method, while Cu3(BTC)2 was synthesized with two electrochemical and solvothermal approaches… read more here.
Keywords: cu3 btc; nh2 cu3; cu3; co2 adsorption ... See more keywords
Defect-rich Graphene Stabilized Atomically Dispersed Cu3 Clusters with Enhanced Oxidase-Like Activity for Antibacterial Applications
Sign Up to like & getrecommendations! Published in 2021 at "Applied Catalysis B: Environmental"
DOI: 10.1016/j.apcatb.2021.120826
Abstract: Abstract Nanozyme has attracted great attention due to its diverse enzymatic catalytic activities. But there are still challenges in constructing novel nanozyme with robust catalytic activity. Here, we report an atomically dispersed and fully exposed… read more here.
Keywords: oxidase like; atomically dispersed; defect rich; dispersed cu3 ... See more keywords
Is Cu3–xP a Semiconductor, a Metal, or a Semimetal?
Sign Up to like & getrecommendations! Published in 2022 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.2c03283
Abstract: Despite the recent surge in interest in Cu3–xP for catalysis, batteries, and plasmonics, the electronic nature of Cu3–xP remains unclear. Some studies have shown evidence of semiconducting behavior, whereas others have argued that Cu3–xP is… read more here.
Keywords: metal semimetal; chemistry; semiconductor metal; cu3 semiconductor ... See more keywords
Guest–Host Complexes of TCNQ and TCNE with Cu3(1,3,5-benzenetricarboxylate)2
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.7b07807
Abstract: A combined spectroscopic and structural study was undertaken to investigate the nature of the incorporation of the electron acceptor guest 7,7,8,8-tetracyanoquinodimethane (TCNQ) and the closely related guest tetracyanoethylene (TCNE) into the host porous framework [Cu3(BTC)2]… read more here.
Keywords: benzenetricarboxylate; framework; guest host; host ... See more keywords
Tunable Carrier Type of a Semiconducting 2D Metal–Organic Framework Cu3(HHTP)2
Sign Up to like & getrecommendations! Published in 2022 at "ACS Applied Materials & Interfaces"
DOI: 10.1021/acsami.2c00089
Abstract: In this work, a switch from n-type to p-type conductivity in electrodeposited Cu3(2,3,6,7,10,11-hexahydroxytriphenylene)2 [Cu3(HHTP2)] has been observed, which is most likely due to oxygen molecular doping. The synthesis of electrically conductive 2D metal–organic frameworks (MOFs)… read more here.
Keywords: carrier type; tunable carrier; metal organic; type ... See more keywords
Identifying the Local Atomic Environment of the "Cu3+" State in Alkaline Electrochemical Systems.
Sign Up to like & getrecommendations! Published in 2023 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.3c01852
Abstract: CuO-based catalysts are active for the oxygen evolution reaction (OER), although the active form of copper for the OER is still unknown. We combine operando Raman experiments and density functional theory (DFT) electronic structure calculations… read more here.
Keywords: identifying local; electronic structure; local atomic; environment cu3 ... See more keywords