Structural Modulation from Cu3PS4 to Cu5Zn0.5P2S8: Single-Site Aliovalent-Substitution-Driven Second-Harmonic-Generation Enhancement.
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DOI: 10.1021/acs.inorgchem.1c00115
Abstract: Diamond-like (DL) chalcophosphates, which possess the merits of impressive second-harmonic-generation (SHG) responses, strong laser-induced damage thresholds, and low melting points, are highly desirable for IR nonlinear-optical (NLO) applications. Herein, a new quaternary DL chalcophosphate, Cu5Zn0.5P2S8,… read more here.
Keywords: harmonic generation; aliovalent substitution; substitution; second harmonic ... See more keywords