Synthesis, crystal structures, magnetic and magnetocaloric studies of heterometallic enneanuclear {Cu7Gd2} complexes
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DOI: 10.1016/j.poly.2020.114960
Abstract: Abstract The reaction of Gd(NO3)3∙6H2O and [Cu2(piv)4(pivH)2] with the polydentate Schiff base ligands o-OH-C10H6-CH=NC(R)(CH2OH)2 (R = CH3, H3L1; R = C2H5, H3L2) in MeOH afforded the enneanuclear heterometallic complexes [Cu7Gd2(L1)4(HL1)2(piv)4(H2O)(MeOH)3] (1) and [Cu7Gd2(L2)4(HL2)2(piv)4(MeOH)5] (2). Crystallographic… read more here.
Keywords: structures magnetic; meoh; cu7gd2; crystal structures ... See more keywords