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Published in 2018 at "Advanced materials"
DOI: 10.1002/adma.201706916
Abstract: As a new category of solids, crystalline materials constructed with amorphous building blocks expand the structure categorization of solids, for which designing such new structures and understanding the corresponding formation mechanisms are fundamentally important. Unlike…
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Keywords:
new ordered;
carbon;
carbon clusters;
amorphous carbon ... See more keywords
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Published in 2021 at "ChemBioChem"
DOI: 10.1002/cbic.202100334
Abstract: Cubane molecules hold great potential for medicinal chemistry applications due to their inherent stability and low toxicity. In this study, we report the synthesis of a cubane derivative phosphoramidite for the incorporation of cubane into…
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Keywords:
building sirnas;
cubes synthesis;
cubane;
sirnas cubes ... See more keywords
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Published in 2017 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201700427
Abstract: The carbon–carbon bonding in cubane is shown not to be along the C–C vectors between carbon atoms at the corners of a cube. Instead, the bonding is “bent” as seen in a new single-crystal X-ray…
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Keywords:
bonds cubane;
cyclopropane;
chemistry;
bent bonds ... See more keywords
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Published in 2018 at "Journal of Cluster Science"
DOI: 10.1007/s10876-018-1406-2
Abstract: A new cubane-based cobalt(II) cluster, [Co4L4] (1), where H2L = 2-((E)-(2-hydroxyethylimino) methyl)-4-chlorophenol has been prepared using a solvothermal process and characterized by structural, optical and magnetism. The crystal structure of 1 consists of a tetranuclear Co4O4 core…
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Keywords:
magnetism;
cobalt;
cubane;
cobalt cluster ... See more keywords
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Published in 2018 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2018.03.071
Abstract: Abstract The nature of interactions between the neutral, charged and substituted cubane, within cucurbituril host were analyzed employing the dispersion corrected density functional theory. The structural comparison between the inclusion complexes of CB7 and CB8…
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Keywords:
inclusion;
energy;
analysis;
nature ... See more keywords
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Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01359
Abstract: It is a great challenging task for selectivity control of both CO2 photoreduction and water splitting to produce syngas via precise microenvironment regulation. Herein, a series of UiO-type Eu-MOFs (Eu-bpdc, Eu-bpydc, Rux-Eu-bpdc, and Rux-Eu-bpydc) with…
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Keywords:
microenvironment;
water splitting;
microenvironment regulation;
cubane ... See more keywords
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Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b00567
Abstract: Heterometallic Zn2Ln2 [Ln = Gd (1), Eu (2), Tb (3), Dy (4)] discrete molecules with edge-defective cubane structure are assembled from a multifunctional fluorescent conjugate ligand and LnIII/ZnII mixed-metal ions; they exhibit the tunable luminescence,…
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Keywords:
heterometallic zn2ln2;
edge defective;
stimuli responsive;
cubane ... See more keywords
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Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.7b01029
Abstract: Cubane, an intriguing chemical curiosity first studied in the early 1960s, has become a valuable structural motif and has recently been involved in the structures of a great number of prospective compounds. The first dicationic…
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Keywords:
cubane arrives;
cucurbituril scene;
cubane;
arrives cucurbituril ... See more keywords
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Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c03528
Abstract: Photosynthetic water oxidation is catalyzed by a manganese–calcium oxide cluster, which experiences five “S-states” during a light-driven reaction cycle. The unique “distorted chair”-like geometry of the Mn4CaO5(6) cluster shows structural flexibility that has been frequently…
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Keywords:
state;
water oxidation;
water;
cubane ... See more keywords
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Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c10878
Abstract: We report the mechanochemical reactivity of the highly strained pentacyclic hydrocarbon cubane. The mechanical reactivity of cubane is explored for three regioisomers with 1,2-, 1,3-, and 1,4-substituted pulling attachments. Whereas all compounds can be activated…
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Keywords:
mechanochemistry cubane;
spectroscopy;
reactivity;
cubane ... See more keywords
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Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b01356
Abstract: Predictive and mechanistically driven access to polynuclear oxo clusters and related materials remains a grand challenge of inorganic chemistry. We here introduce a novel strategy for synthetic control over highly sought-after transition metal {M4O4} cubanes.…
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Keywords:
mechanistically driven;
control;
chemistry;
h2o ... See more keywords