A cubane-type nickel single-molecule magnet with exchange-biased quantum tunneling of magnetization
Sign Up to like & getrecommendations! Published in 2020 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2020.03.012
Abstract: Low temperature magnetization measurements were performed on single crystals of the pyridyl-alcohol-supported [Ni(μ3-Cl)Cl(HL·S)]4 coordination cluster and they revealed open hysteresis loops up to 30 mK at a sweep rate of 0.07 T s−1. The studied… read more here.
Keywords: molecule; single molecule; cubane type; molecule magnet ... See more keywords
Fe4S4 Cubane Type Cluster Immobilized on a Graphene Support: A High Performance H2 Evolution Catalysis in Acidic Water
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DOI: 10.1038/s41598-017-17121-7
Abstract: The development of alternate catalysts that utilize non-precious metal based electrode materials such as the first row transition metal complexes is an important goal for economic fuel cell design. In this direction, a new Fe4S4… read more here.
Keywords: fe4s4 cubane; evolution; cubane type; cluster immobilized ... See more keywords
A cubane-type manganese complex with H2O oxidation capabilities
Sign Up to like & getrecommendations! Published in 2020 at "Sustainable Energy and Fuels"
DOI: 10.1039/d0se00701c
Abstract: We report the synthesis and characterisation of [Mn8K2O4(OH)2((CH3)3CCOO)16(CH3CN)2] whose cluster core shares some features with the oxygen evolving complex (OEC), the natural water oxidation catalyst. Importantly, this complex provides a bio-inspired complex that promotes catalytic… read more here.
Keywords: cubane type; h2o oxidation; oxidation; type manganese ... See more keywords