Tri- and pentanuclear CuII–CdII complexes of N2O2 donor ligands with the variation of carboxylate coligands: Structural elucidation and theoretical study
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DOI: 10.1016/j.ica.2021.120351
Abstract: Abstract Three new heterometallic copper(II)-cadmium(II) complexes [(CuL1)2Cd3(C6H5CO2)6] (1), {[(CuL2)2Cd(o-(NO2)C6H4CO2)2]·2NCMe} (2), and [{CuL2(H2O)0.65(NCMe)0.35}2Cd3(m-(NO2)C6H4CO2)6] (3) have been synthesized using [CuL1]/[CuL2] as metalloligand (where H2L1 = N,N′-bis(2-hydroxynaphthyl-methylidene)-1,3-propanediamine, H2L2 = N,Ń-bis(methyl2-hydroxynaphthyl-methylidene)-1,3-propanediamine). Single crystal structure analyses reveal that complexes 1… read more here.
Keywords: cuii cdii; pentanuclear cuii; cdii; tri pentanuclear ... See more keywords