A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity.
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DOI: 10.1021/jacs.1c00260
Abstract: The central role of cupric superoxide intermediates proposed in hormone and neurotransmitter biosynthesis by noncoupled binuclear copper monooxygenases like dopamine-β-monooxygenase has drawn significant attention to the unusual methionine ligation of the CuM ("CuB") active site… read more here.
Keywords: atom abstraction; hydrogen atom; cupric superoxide; reactivity ... See more keywords