Progress toward the Enantioselective Synthesis of Curcusones A-D via a Divinylcyclopropane Rearrangement Strategy.
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DOI: 10.1021/acs.orglett.9b03829
Abstract: We report our iterative efforts toward the divergent total syntheses of curcusones A-D via Suzuki coupling, intramolecular cyclopropanation, and a key divinylcyclopropane rearrangement. Progress of our synthesis was repeatedly challenged by the highly substrate-dependent cyclopropanation… read more here.
Keywords: curcusones via; progress toward; synthesis; divinylcyclopropane rearrangement ... See more keywords