The First Copper(I)-Olefin Complexes Bearing a 1,3,4-Oxadiazole Core : Alternating-Current Electrochemical Crystallization, X-ray Experiment and DFT Study
Sign Up to like & getrecommendations! Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2017.05.052
Abstract: Abstract By means of alternating-current electrochemical technique, four new π-complexes, namely [Cu2(C11H10N2OS)2Br1.91Cl0.09] (1), [Cu(C11H10N2OS)NO3] (2), [Cu2(C11H10N2OS)2(H2O)2](BF4)2 (3) and [Cu2(C11H10N2OS)2(H2O)2](ClO4)2 (4), were obtained using copper(II) salts and the 2-(allylthio)-5-phenyl-1,3,4-oxadiazole (C11H10N2OS) ligand. The metal and halogen centers… read more here.
Keywords: cu2 c11h10n2os; dft; c11h10n2os; current electrochemical ... See more keywords
Current electrochemical approaches to selective deuteration.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00344a
Abstract: The selective deuteration of organic molecules through electrochemistry is proving to be an effective alternative to conventional 2H labelling strategies, which traditionally require high temperatures, high pressures of deuterium gas in hydrothermal autoclave reactors, or… read more here.
Keywords: deuteration; selective deuteration; current electrochemical; electrochemistry ... See more keywords