Solvent-Mediated Enantioselective Rauhut-Currier Cyclization via Iminium and Enamine Activation.
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DOI: 10.1021/acs.orglett.2c04249
Abstract: In this work, we have developed an unconventional and highly enantioselective solvent-promoted Rauhut-Currier cyclization of enal-tethered cyclohexadienone by exploiting the reactivity of a simple Jørgensen-Hayashi catalyst through the merging of iminium and enamine activation. This… read more here.
Keywords: enamine activation; iminium enamine; solvent; rauhut currier ... See more keywords