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Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c01642
Abstract: This study explores a bottom-up approach toward negatively curved carbon allotropes from octabenzo[8]circulene, a negatively curved nanographene. Stepwise chemical reduction reactions of octabenzo[8]circulene with alkali metals lead to a unique highly reduced hydrocarbon pentaanion, which…
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Keywords:
curved carbon;
curved nanographene;
covalent network;
negatively curved ... See more keywords